シクロフェニレン骨格での置換基の電子伝達機構 [Published online J. Comput. Chem. Jpn., 18, 147-149, by J-STAGE]

[Published online Journal of Computer Chemistry, Japan Vol.18, 147-149, by J-STAGE]
<Title:> シクロフェニレン骨格での置換基の電子伝達機構
<Author(s):> 亮治藤山, あゆみ井上, 夢月原田
<Corresponding author E-Mill:> fujiyama(at)kochi-u.ac.jp
<Abstract:> In order to examine the transmision of electronic effects in cyclophenylene framework, substituent effects on some cyclophenylene derivatives with primary carbocation CH₂⁺ were carried out. The substituent effects on the energy of isodesmic reactions were analyzed by the LSFE equation that separates the inductive and the resonance effects . The analysis results indicate that the counterclockwise and the clockwise resonances shown in the Figure are mainly important.
<Keywords:> Cyclophenylene, Substituent effect, LSFE equation, Resonance effect, Biphenylene
<URL:> https://www.jstage.jst.go.jp/article/jccj/18/3/18_2019-0018/_article/-char/ja/

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